Stories From Sodor Wikia
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So, something I decided to do is list all characters alphabetically listing each of their debuts in each series. So, here we go.

A-I

Character SFS JAFAGU SFSF IFATW
Dodge 01.03.Saving Benjamin N/A 05.17.Splodge Off Sodor N/A
Donald and Douglas 01.01.Emily to the Rescue N/A 01.01.Duck's Special Job (cameo)
04.10.Gordon and the Scottish Twins (first speaking role)
18.14.Scots In Ireland
Duchess N/A 05.17.Splodge Off Sodor 18.09.Duchess
Duck 01.01.Emily to the Rescue (cameo)
01.02.Memories (first speaking role)
01.01.Jacob's New Job 01.01.Duck's Special Job 01.01.Untitled Duck, Chloe, Dennis, and Chinansa Episode
Edward 01.01.Emily to the Rescue (cameo)
01.02.Memories (first speaking role)
01.05.Old Edward 02.06.A Gemmy Christmas 13.02.Jacob Back In China (mentioned)
Gordon 01.01.Emily to the Rescue 02.01.Sierra Comes Home (cameo) 02.06.A Gemmy Christmas 03.06.The Great Race?
Henry 01.01.Emily to the Rescue 01.06.Saved From Scrap 02.06.A Gemmy Christmas (cameo)
04.02.Henry and Spencer (first speaking role)
08.12.The God of Death

J-R

Character SFS JAFAGU SFSF IFATW
James 01.01.Emily to the Rescue N/A 02.06.A Gemmy Christmas (cameo)
04.01.Toby and James (first speaking role)
04.02.Untitled James and Analise Episode
Oliver the Engine 01.01.Emily to the Rescue N/A 01.01.Duck's Special Job (cameo)
04.03.Oliver and Percy (first speaking role)
N/A
Percy 01.01.Emily to the Rescue 01.06.Saved From Scrap (cameo) 02.06.A Gemmy Christmas 19.07.A Visit from Percy

S-Z

Character SFS JAFAGU SFSF IFATW
Splatter 01.03.Saving Benjamin N/A 05.17.Splodge Off Sodor N/A
Thomas 01.01.Emily to the Rescue (cameo)
01.02.Memories (first speaking role)
01.06.Saved From Scrap (cameo) 01.04.Story Time Part 1 (mentioned)
04.17.Thomas, Percy, and Duck (first speaking role)
18.13.Thomas and Saoirse
Toby 01.01.Emily to the Rescue (cameo)
01.02.Memories (first speaking role)
N/A 04.01.Toby and James 04.14.Axel and Toby
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